| 학회 |
한국고분자학회 |
| 학술대회 |
2022년 봄 (04/06 ~ 04/08, 대전컨벤션센터) |
| 권호 |
47권 1호 |
| 발표분야 |
고분자구조 및 물성 |
| 제목 |
Macroporous Polyimide with High Porosity via Precursor Mediated Emulsion Templating |
| 초록 |
Poly(amic acid) salt (PAAS) is an amphiphilic molecule that a lipophilic polymer backbone is conjugated with the hydrophilic organic bases, which is a precursor to be converted to polyimide via thermal imidization process. The PAAS is known as stabilizes the interface of water and oil, even up to internal volume ＞74 vol% that is high internal phase emulsion (HIPE). But still, a few of the PAAS has been considered as an emulsifier due to the lack of a basic study on the correlation between their chemical structure and interfacial activity. In this study, we explore the combinations of poly(amic acid) and organic bases that are suitable for stabilizing the oil-water interfaces to build the HIPE. We also present the preparation of macroporous polyimide by using freeze-drying and thermal imidization processes. By doing so, we will propose the preparation method for thermally-stable macroporous polyimide with high porosity and 3D continuous structure having various chemical structures. |
| 저자 |
김선규1, 박종민2, 소유진1, 김윤호1, 고민재1, 원종찬2
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| 소속 |
1한국화학(연), 2한양대 |
| 키워드 |
Polyimide; HIPE; FOAM; Macroporous polymer; PAAS
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| E-Mail |
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