화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 고분자 합성
제목 Dispersion Polymerization of Methyl Methacrylate in Supercritical Carbon Dioxide Using Random Copolymeric Stabilizers
초록 A series of random copolymer, composed of 2,2,3,3,4,4,4-heptafluorobutyl methacrylate and 2-(diisopropylamino)ethyl methacrylate, poly(FBMA-co-DPAEMA) with different ratio were prepared and could be utilized as stabilizers in the dispersion polymerization of methyl methacrylate in supercritical carbon dioxide. The morphology of poly methyl methacrylate parcticles investigated by SEM. The crystallite size of the poly methyl methacrylate increased from 2 to 6 ㎛with the contains of FBMA decreased 65 to 37 wt% in poly (FBMA-co-DPAEMA).
저자 우민희, 김준호, 김원수, 임권택
소속 부경대
키워드 dispersion polymerization; poly methyl methacrylate; polymeric stabilizer; supercritical carbon dioxide; random copolymer
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