| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
37권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Pseudo-crystalline mesoporous structures created by collapse of polymersomes of dendritic-linear block copolymers |
| 초록 |
We report new pseudo-crystalline mesoporous structures formed by collapse of polymer vesicles (polymersomes) made from the self-assembly of block copolymers built on a dendritic hydrophilic block. For this study, we synthesized block copolymers based on a dendritic poly(ethylene glycol) hydrophilic block, which was composed of short peripheral PEG chains. The collapse of polymersomes was induced by the instability of the bilayer membrane caused from the 'crew-cut' nature of hydrophilic corona of the bilayer. We examined the kinetic pathway of the collapse of polymersomes by tracing the self-assembly process via quenching experiments. TEM visualization of the self-assembly process of dendritic-linear block copolymers revealed an entirely new morphology obtained from block copolymer self-assembly in solution. |
| 저자 |
라윤주, 정문곤, 안태현, 김경택
|
| 소속 |
UNIST |
| 키워드 |
dendritic-linear block copolymers; polymersomes; morphology
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| E-Mail |
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