| 학회 | 한국공업화학회 |
| 학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
| 권호 | 26권 1호 |
| 발표분야 | 포스터-고분자 |
| 제목 | Imparting the flame retardancy to the polymethylsilsesquioxane (PMSQ) aerogel monolith by introducing 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO)-derivatives. |
| 초록 | In an attempt to improvethe flame retardancy of the PMSQ aerogel, an environmentally friendly flame retardantcompound named DOPO is used and this can be combined with a vinyltrimethylsiloxane(VTMS) agent by 1:1 molar ratio for being a part of PMSQ network. This synthesizedPMSQ aerogel doesn’t only prevent emitting hazardous substances due to the halogen-freeflame-retardant material. DOPO-VTMS can be characterized by 1H, 31PNMR (nuclear magnetic resonance) and DOPO-VTMS PMSQ aerogel can be investigatedby SEM (scanning electron microscope), and BET (Brunauer-Emmett-Teller) to differentiatetwo different aerogels and DOPO-VTMS PMSQ aerogel. Specifically, it is shownthat the thermal stabilities enhanced and the decomposition mechanisms differedby showing each nitrogen and air atmosphere of TGA (thermal gravimetric analysis).The excellent 60% reduction of the heat release rate (HRR) occurred byintroducing DOPO-VTMS in the PMSQ aerogel by analyzing with the microcalorimeters. |
| 저자 | 박예서, 심상은, 민경훈 |
| 소속 | 인하대 |
| 키워드 | DOPO; flame retardancy; polymethylsilsesquioxane aerogel |
