화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2006년 가을 (11/10 ~ 11/11, 경희대학교(수원캠퍼스))
권호 10권 2호
발표분야 촉매
제목 Effect of Dispersed MoO3 Amount on Catalytic Activity of NiO-ZrO2 Modified with MoO3 for Acid Catalysis
초록 MoO3 equal to or less than 15 wt% was dispersed on the surface of catalyst, while for MoO3 above 15 wt%, crystalline orthorhombic phase of MoO3 was formed, showing that the critical dispersion capacity of MoO3 on the surface of catalyst is 0.18 g/g NiO-ZrO2 on the basis of XRD analysis. Acidity and catalytic activities for acid catalysis increased with the amount of dispersed MoO3. The high acid strength and acidity was responsible for the Mo=O bond nature of the complex formed by the interaction between MoO3 and ZrO2. The catalytic activity was correlated with the acidity of the catalysts measured by the ammonia chemisorption method.
저자 손종락, 이성규, 신동철
소속 경북대
키워드 NiO-ZrO2/MoO3 Catalyst; MoO3 dispersion; Acid Catalysis; 2-propanol Dehydration; Cumene Dealkylation
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