| 학회 |
한국고분자학회 |
| 학술대회 |
2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터) |
| 권호 |
39권 1호 |
| 발표분야 |
고분자가공/복합재료- 미래 자동차용 고분자소재 최신기술 동향 |
| 제목 |
Functionalized Mesoporous Silicas for Selective Adsorption of Copper Ions in Artificial Seawater |
| 초록 |
We studied on the adsorption of Cu2+ with high selectivity using imprinted ligand moieties-functionalized mesoporous silica materials in the artificial seawater. Imprinted ligand moieties were synthesized on the mesopore surface of SBA-15 via complexation process of Co2+ and chemical combination of amine group and epichlorohydrin. Mesoporous silica, SBA-15 with imprinted ligands was ascertained by XRD, TEM and BET for the well-retained mesostructure and by FTIR and UV-vis spectra for the functionalized ligands. After leaching out of Co2+, the absorbent was used for the selective adsorption of Cu2+ ion in solution with various metal ions (Cr2+, Ni2+, Co2+, Cu2+ and Li+) using artificial seawater as solvent. The selectivity of metal ions was 69 % for Cu2+, 21 % for Cr2+, 5 % for Ni2+, 3 % for Li+ and 2 % for Co2+, respectively. The high selectivity toward Cu2+ of Co2+-imprinted ligands may be due to the distorted ligand structure after leaching out of Co2+. |
| 저자 |
박성수, 송현진, 산타무티, 매튜아니쉬, 하창식
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| 소속 |
부산대 |
| 키워드 |
mesoporous silica; adsorpiton; cooper ion
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| E-Mail |
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