| 학회 |
한국화학공학회 |
| 학술대회 |
2003년 가을 (10/24 ~ 10/25, 한양대학교) |
| 권호 |
9권 2호, p.2915 |
| 발표분야 |
촉매/반응공학 |
| 제목 |
Preparation of dihydroxylbenzene through clean production technology |
| 초록 |
Phenol hydroxylation with H2O2 has performed in batch reactor at a temperature of 20~70oC over various Ion- exchanged zeolites. Ion-exchanged zeolite with Fe2+ and Co2+ cations is very active and selective for dihydroxybenzenes in phenol hydroxylation with H2O2 in aqueous reaction medium at room temperature. Ion-exchanged zeolite with Fe2+ and Co2+ cations shows high catalytic activity at room temperature in phenol hydroxylation with H2O2, where the conversion of phenol is 21% and the selectivity of benzoquinone is below 3% at the molar ratio of phenol to H2O2 of 3 in the starting aqueous reaction medium. Metal ions exchanged into supercages and/or channels of zeolite are supposed to act as active centers for the reaction. |
| 저자 |
박중남1, 이철위1, 김진원1, 박용기1, 정한철2, 송인표2, 최광식2, 홍석인3
|
| 소속 |
1한국화학(연), 2애경화학 기술(연), 3고려대 |
| 키워드 |
Hydroxylation; Phenol; H2O2; Catalyst |
| E-Mail |
|
| 원문파일 |
초록 보기 |
