화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2007년 가을 (10/26 ~ 10/27, 한국과학기술원)
권호 13권 2호, p.1812
발표분야 에너지/환경
제목 Effect of high concentration and long time reaction on the metal corrosion in decomposition of 2-chlorophenol by Supercritical Water Oxidation
초록 Recently, we reported on the continuous anti-corrosive SCWO reactor system, which installed a ceramic tube into a reactor. By controlling temperature and pressure, the supercritical zone is floated at the middle of the reactor and the reaction occurs only inside the ceramic tube. We experiment decomposition 2-chlorophenol with zirconium 702 metal coupon at 2 hours reaction, and at high concentration 2-chlorophenol. We acquired decomposition and corrosion data for scale up this anti-corrosive SCWO reactor system. Corrosion phenomena data was investigated at the supercritical conditions and Zirconium 702 was selected as tested materials. AES-SAM was used to conduct the surface chemical analysis. Oxygen penetration in the alloy was found at supercritical conditions and the penetration depth was deeper at high concentration reaction.
저자 이재혁, 손상하, 이동근, 이재욱, 이창하
소속 연세대
키워드 Supercritical water oxidation; Anticcorosive; Corrosion
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