화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2014년 봄 (04/10 ~ 04/11, 대전 컨벤션센터)
권호 39권 1호
발표분야 고분자구조 및 물성
제목 Recycling method for Silane-XLPE resin via supercritical methanol and compounding process
초록 The silane-crosslinked polyethylene (S-XLPE) does not dissolve in solvents and melt by heat due to the crosslinked network structure. Therefore, it is very difficult to reuse such a crosslinked resin. Most of waste crosslinked polyethylene have been incinerated or disposed of in landfills. We investigated the method to recover thermoplastic polyethylene (decrosslinking) from silane-crosslinked polyethylene cables using supercritical methanol. Moreover, we compounded decrosslinked S-XLPE with LLDPE which is a base resin of S-XLPE cable in order to testifiy reuse of recycled S-XLPE.The degree of cross-linking, physical, thermal, structucture and rheological properties of products were analyzed using DSC,TGA,FTIR,Tensile and Impact tester and Physica UDS.Successful recycling of Silane-crosslinked polyethylene was achieved by supercritical fluids and compounding process.
저자 백범기1, 홍순만1, 구종민1, 한학수2
소속 1한국과학기술(연), 2연세대
키워드 Silane-crosslinked XLPE; decrosslinking; supercritical methanol; compounding
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