| 학회 |
한국고분자학회 |
| 학술대회 |
2015년 가을 (10/06 ~ 10/08, 대구컨벤션센터(EXCO)) |
| 권호 |
40권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Facile Synthesis of Metal Nanoparticles by Green Synthetic Protocols with Dumbbell-type Hyperbranched Polyglycidol |
| 초록 |
A series of dumbbell-type hyperbranched polyglycidol (dHBP) with different molecular weights have been synthesized via an anionic ring-opening multi-branching polymerization of glycidol using α,ω–amine terminated poly(propylene oxide) (molecular weight 230) as an initiator.The dHBP played role as an effective reducer and stabilizer for the synthesis of highly water-soluble monometallic (Au and Ag) nanoparticles in the absence of any additional reducers and surfactants. The dHBP-assisted reduction of metal ions follows an analogous polyol process. The size and shape of nanoparticles is controlled by simply changing the concentration of the metal ion precursor and dHBP dissolved. The optical properties of the as-prepared metal nanoparticles are investigated by UV-vis spectroscopy and their structural characteristics were defined by transmission electron microscope image. The size of these nanoparticles was measured by dynamic light scattering. |
| 저자 |
김일1, 박희주2
|
| 소속 |
1BK21 플러스 동남권화학신기술 창의인재양상사업단, 2부산대 |
| 키워드 |
Dumbbell-type hyperbranched polyglycidol; Ring-opening multi-branching polymerization; reducing agent; metal nanoparticles
|
| E-Mail |
|
