학회 |
한국공업화학회 |
학술대회 |
2009년 가을 (10/15 ~ 10/16, 서울산업대학교 내 서울테크노파크) |
권호 |
13권 2호 |
발표분야 |
환경에너지(포스터) |
제목 |
Photolysis of Aqueous Perfluorinated Compounds |
초록 |
This studyreports on the oxidative and reductivedegradations ofperfluoro alkyl carboxylates and sulfonates with different chain lengths in UV254-irradiated iodide and persulfate solutions. The ionic headgroup (-SO3- vs. -CO2-) has a significant effect on thedegradation kinetics and extent of defluorination. Perfluoro alkyl sulfonate reduction kinetics and the F-Index increase linearly with increasing chain length. In contrast, perfluoro alkyl carboxylate chain length appears to have a negligible effect on the observed kinetics and the F-Index.H/F ratios in the gaseous fluoroorganic products are consistent with measured F-indexes. |
저자 |
박현웅, 김영광, 박아영
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소속 |
경북대 |
키워드 |
Photolysis; Pefluorinated Compounds; Iodide; Persulfate
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E-Mail |
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