화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2019년 가을 (10/23 ~ 10/25, 대전컨벤션센터)
권호 25권 2호, p.2177
발표분야 Nexus of Separation and Energy Technology Symposium (분리기술부문위원회)
제목 Experimental and Modeling Study of CO2 Solubility in Aqueous Blended Amine Solutions for Estimating Regeneration Energy of Post Combustion Carbon Capture Process
초록 Newly measured experimental data of CO2 solubilities in aqueous MEA (primary), DIPA (secondary), MDEA (tertiary), AMP (steric hindrance) and their mixture solutions are provided with thermodynamic models, such as Kent Eisenberg, Deshmukh Mather, and electrolyte NRTL models. The solubility measurements were carried out over a wide temperature range and at various amine concentration conditions with static method. The successive substitution method was introduced for calculating mole fractions of all electrolytes from equilibrium, material and charge balance equations simultaneously. CO2 partial pressure, liquid phase concentrations for all components including carbamates, pH, and the heats of absorption for all amine concentrations, temperatures, and CO2 loading conditions could be obtained. Also a simple method to estimate the regeneration energy in amine-based wet scrubbing processes was proposed.
저자 문종호1, 이종섭2, 최봉근1, 박영철2, 전동혁2, 신헌용3, 성현제4, 민병무2
소속 1충북대, 2한국에너지기술(연), 3서울과학기술대, 4한솔EME
키워드 이산화탄소; 용해도; 습식포집; 활동도; 재생에너지
E-Mail
VOD VOD 보기
원문파일 초록 보기