| 학회 | 한국공업화학회 |
| 학술대회 | 2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 | 19권 2호 |
| 발표분야 | 환경에너지_포스터 |
| 제목 | Multi-step Synthesis of 5-Acetoxylmethyl-2-furfural (AMF) from D-Fructose |
| 초록 | 5-Hydroxymethyl-2-furfural (HMF) and its derivatives are among the promising biomass-derived platform chemicals, which have the potential to become “carbon-neutral” feedstock or building blocks in a green, renewable and sustainable industry. However, the current methods for HMF production from D-Fructose have several drawbacks such as the use high boiling solvents and difficulties in product purification. Comparing to HMF, 5-acetoxylmethyl-2-fufural (AMF) is considered to be more thermal stable and rather easier to isolate. In this research, rather than transforming D-Fructose into HMF in aprotic polar solvents such as DMSO, we are trying to synthesize AMF by direct dehydration of 1,6-Diacetyl-fructofuranose (DAF), a di-ester derivation of D-Fructose. This approach has the advantage of avoiding the difficulties related to HMF purification since AMF can be isolated from the reaction mixture by recrystallization or vacuum distillation. |
| 저자 | 조진구, Tan Phat Nguyen, Vo Thi Hoang Anh, 문다솜, 박석규, 김보라, Huynh Thanh Thien Nhan |
| 소속 | 한국생산기술(연) |
| 키워드 | D-Fructose; AMF; HMF |
