화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2009년 봄 (04/09 ~ 04/10, 대전컨벤션센터)
권호 34권 1호
발표분야 기능성 고분자
제목 A liquid crystal embedded PVdF-co-HFP-based quasi-solid state electrolyte for dye-sensitized solar cell applications
초록 Liquid crystal (LC) embedded poly(vinylidenefluoride-co-hexafluoropropylene) (PVdF-co-HFP) based quasi solid state electrolytes have been used for dye-sensitized solar cells (DSSCs). Electrolyte contains 1-methyl-3-propylimidazolium iodide (PMII), tetrabutylammonium iodide (TBAI), iodine (I2) as the source of redox couple (I3-/I-) and the quasi solid state electrolyte behavior was improved by the addition of optimized plasticizer contents such as ethylene carbonate (EC) and propylene carbonate (PC) in an acetonitrile. We have fabricated DSSCs and employed liquid crystal (E7 and/or ML-0249) embedded quasi solid state electrolyte between the amphiphilic ruthenium dye (N719) adsorbed nanocrystalline TiO2 photoanode and Pt counter electrode. Consequently, the liquid crystal embedded polymer based quasi solid state electrolytes showed higher photocurrent, photovoltage and effiency than the only PVdF-HFP based electlolyte.
저자 김설미1, G. Vijayakumara1, 이명진1, 류태인1, 진성호1, 제갈영순2
소속 1부산대, 2경일대
키워드 DSSC; electrolyte
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