화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2021년 가을 (11/03 ~ 11/05, 대구 엑스코(EXCO))
권호 25권 2호
발표분야 포스터-고분자
제목 Synthesis of Amphiphilic Cationic Block Copolymer and Its application as Surfactant for Fabrication of Thin-Film Composite Reverse Osmosis Membrane
초록 Thin film composite (TFC) reverse osmosis (RO) membranes show superior separation performance for water desalination process compared to other types of membranes. However, trade-off relationship between the water permeance and the selectivity exists for the TFC RO membranes. In order to overcome this relationship and endow the membranes with other properties, many kinds of materials have been introduced to TFC membranes as additives. Among various types of additives, surfactant, especially polymeric surfactant has the advantage over monomeric surfactant that it can remain in the membranes after the interfacial polymerization, and also act as fillers, so it can change the surface properties of the RO membranes. In this study, amphiphilic cationic block copolymer was synthesized via RAFT polymerization and subsequent quaternization, and incorporated into the selective layer of TFC RO membranes. As a result, separation performance of the membranes can be improved.
저자 김문현, 김재준, 서희란, 정경화, 이종찬
소속 서울대
키워드 Amphiphilic block copolymer; Polymeric surfactant; Reverse osmosis; Water desalination
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