| 학회 |
한국고분자학회 |
| 학술대회 |
2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터) |
| 권호 |
38권 2호 |
| 발표분야 |
분자전자 부문위원회 |
| 제목 |
The Effect of Cyano Substituent on Nano-Scale Morphology of Bulk Heterojunction Solar Cells |
| 초록 |
The morphological and photovoltaic characteristics of naphthalene-based conjugated polymers:PC71BM blends are studied with and without cyano substituted group as an electron deficient group on a conjugated polymer. PBTADN:PC71BM blend solar cells exhibited an extended optical absorption over the solar spectrum and homogeneous nano-scale morphology that enhanced charge carrier transport compared to PBTDN:PC71BM which does not possess cyano substituent. Without annealing processing, the bulk-heterojunction devices of PBTADN:PC71BM blend yielded an open circuit voltage (VOC) of 0.89 V,a current density (JSC) values of 7.4 mA/cm2, a fill factor (FF) of 0.51, and power conversion efficiency (PCE) values of 3.4 %, showing highly increased VOC and FF with respect to PBTDN:PC71BM blend solar cells. This study suggests that the conjugated polymer including cyano substituted group has distinct advantages for the development of highly efficient polymer solar cells. |
| 저자 |
차효정1, 김슬옹2, 권순기2, 김윤희2, 박찬언1
|
| 소속 |
1포항공과대, 2경상대 |
| 키워드 |
Cyano Substituent; Organic Solar Cells; Semiconducting Polymer; Morphology Control; Conjugated Polymer; Phase Separation
|
| E-Mail |
|
