화학공학소재연구정보센터
학회 한국재료학회
학술대회 2021년 가을 (11/24 ~ 11/26, 경주 라한호텔)
권호 27권 2호
발표분야 C. 에너지 재료 분과
제목 Suitable Anti-solvent for Depositing Uniform Perovskite Regardless of Relative Humidity of Ambient Air
초록 Perovskite solar cells have achieved rapid growth in power conversion efficiency (PCE) and attained 25.2 % recently. Mostly, high-efficiency perovskite solar cells have been prepared with uniform perovskite film by the one-step spin coating method using anti-solvent. Other groups have reported the change of perovskite’s morphology with applying various anti-solvents. Because chemical properties of anti-solvent (e.g. boiling point, polarity, and dielectric constant) affect the film morphology of perovskite. Especially, the dripping process of anti-solvent needs to be optimized to attain high-coverage and uniform perovskite films. However, previous studies have mainly shown the deposition of perovskite at N2-filled glove box and controlled humidity (< RH 20 %). It is necessary to understand how anti-solvent affects the formation of perovskite depending on humidity. In this study, we propose Diethyl ether as an anti-solvent that can achieve high-coverage and uniform perovskite films in ambient humidity conditions (< RH 50 %) by analyzing the UV-vis absorption, scanning electron microscope, and X-ray diffraction spectra of perovskite films.
저자 정석현1, 김동환1, 이원규1, 이솔희1, 이상원1, 황재근1, 강윤묵2, 이해석3
소속 1고려대, 2KU-KIST 그린스쿨대, 3KU-KSIT 그린스쿨대
키워드 Perovsktie solar cell; Relative humidity; Anti-solvent; Ambient air condition; Uniform perovskite
E-Mail