화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 대학원생 구두발표
제목 Continuous Phase Transition from LDOT to UODT
초록 The phase behavior of blends of block copolymers (BCPs) is an interesting topic with respect to phase separation behavior. The phase behavior of BCP has been known to exhibit a microphase separation from an ordered to a disordered state either upon cooling or upon heating, where the latter behavior is called the order-disorder transition (ODT) with enthalpic origin, and the former can be induced by entropic origin, denoted to the lower disorder-order transition (LDOT). Therefore, if these block copolymers were fully miscible, the coexistence of phase transitions may be observed. In this study, we investigated the phase behavior in the blend of block copolymers, which have different type of phase behavior, using small angle X-ray scattering (SAXS), small angle neutron scattering (SANS), depolarized light scattering (DLS), and differential Scanning Calorimetry (DSC).
저자 이용훈, 안형주, 이호연, 류두열
소속 연세대
키워드 블록 공중합체; 상거동; order-to-disorder transition(ODT); lower disorder-to-order transition (LDOT)
E-Mail