화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2004년 가을 (10/08 ~ 10/09, 경북대학교)
권호 29권 2호, p.423
발표분야 분자전자 부문위원회
제목 Synthesis and Characterization of Thermally Crosslinkable Fluorene Oligomers
초록 Fluorene Oligomers containing thermally crosslinkable end-groups were synthesized and their optical properties of the solutions and the films were characterized by UV-Vis absorption and photoluminescence spectroscopy. Liquid crystalline behaviors of the oligomers were also examined by the polarized optical microscope and differential scanning calorimetry. Mono-domain films of cross-linked polymers were obtained by thermally curing the mono-domain oligomer films aligned on the rubbed polymer surface. The cured polymer films exhibit a much higher glass transition temperature and more robust mechanical properties, as compared with those of the oligomers. The detailed anisotropic characteristics of optical absorption and emission of the cured mono-domain polymer films film will be discussed.
저자 이선영, 조정호, 윤도영
소속 서울대
키워드 oligofluorene; mono-domain; curing
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