| 학회 |
한국고분자학회 |
| 학술대회 |
2010년 봄 (04/08 ~ 04/09, 대전컨벤션센터) |
| 권호 |
35권 1호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Multi-metal cyanide complex catalyzed ultra-low and functional polyols |
| 초록 |
Multi-metal cyanide (MMC) compounds representing structures based on a simple cubic M[M’(CN)6] framework, in which octahedral [M’(CN)6]n- complexes are linked via octahedrally coordinated, nitrogen-bound Mn+ ions are well-known catalyst for the polymerization of epoxides and the synthesis of propylene oxide (PO) based polyether polyols (PPG) which are used for polyurethane applications. The resulting catalysts are versatile in that they show very high activity in epoxides/carbon dioxide copolymerizations give polyols with aliphatic carbonate backbones and epoxides/acid anhydride copolymerizations to give polyols with ester backbones as well as epoxide homopolymerizations to give typical polyether polyols. Here we present developments of multimetal cyanide catalyzed (co)polymerizations of epoxides and future outlook. |
| 저자 |
김일, 조정규, 공아름, 윤지환, 유리 쉬푸노프, 최혜윤
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| 소속 |
부산대 |
| 키워드 |
catalysis; transition metals; ring-opening polymerization; epoxides
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| E-Mail |
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