화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2008년 가을 (10/23 ~ 10/24, 부산 BEXCO)
권호 14권 2호, p.3492
발표분야 촉매 및 반응공학
제목 Hydrogen generation from sudiumborohydrideusing Co-Bpowder catalyst
초록 Generation of hydrogen via the hydrolysis of sodium borohydride (NaBH4) solution in the presence of metal catalysts is a promising method for hydrogen storage. For hydrogen generation form a NaBH4 solution. Co-B catalyst was prepared by the chemical reduction method using NaBH4 and CoCl2 as a reduction chemical. The characters of Co-B catalyst were studied by using scanning electron microscopy(SEM), nitrogen adsorption-desorption, FT-IR, and energy dispersive sepectroscopy(EDS).Effect of solvent compound ratio, feeding rate of solvent and amount of catalyst loading on hydrogen generation rate were investigated. Solvent dissolving NaBH4 was Methanol (MeOH), 5wt% NaOH solution, and mixture. We were used to pump for feeding solvent in reactor. The pump rate was between 1 ml/min and 100ml/min.
저자 이정인1, 정종필1, 장성철1, 방준하2, 남석우1, 최대기1
소속 1한국과학기술(연), 2고려대
키워드 hydrogen generation; Cc-B catalyst; methanol; Sodium borohydride
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