| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.1349 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Effect of Pretreatment on the Activity of Fe-Cu-K-Al Fischer-Tropsch Catalyst for BTL Technology |
| 초록 |
The effect of calcination and reduction temperatures on the activity of Fe-Cu-K-Al catalyst for the CO hydrogenation reaction has been studied. The catalyst was prepared by the Co-precipitation method and calcined and reduced at various temperatures. Catalyst characterization techniques such as XRD, TPR, TGA, hydrogen chemisorption, O2-titration were also used. The calcination temperature was found to have a pronounced effect on the overall activity of the catalyst but not on the intrinsic activity of the catalyst sites. On the other hand, the reduction temperature had only a negligible effect on the overall and intrinsic activities. The decrease in rate at high calcination temperatures was caused by a decrease in the number of surface active sites due to a decrease in the reducibility of the catalyst. Neither the reduction nor the calcination conditions had any effect on chain growth probability. |
| 저자 |
송상훈1, 김윤하2, 이상봉1, 박은덕2, 설용건3
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| 소속 |
1한국화학(연), 2아주대, 3연세대 |
| 키워드 |
Fischer-Tropsch; calcination; reducibility; BTL
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| E-Mail |
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| 원문파일 |
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