화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2019년 봄 (05/01 ~ 05/03, 부산 벡스코(BEXCO))
권호 23권 1호
발표분야 콜로이드·계면화학_포스터
제목 Synthesis and properties of Polyoxyethylene cetyl ether maleic acid diesters
초록 In this study, a gemini type reactive surfactants were synthesized. The surfactants has a functional group capable of acting as a monomer in the polymerization and an emulsifier. Polyoxyethylene (5, 10, 15, 20) cetyl ether and maleic acid were used. The structure of the synthesized surfactants was confirmed by FT-IR and 1H-NMR. The surface tension, critical micelle concentration, HLB, foaming height and emulsion stability were evaluated to confirm the physical properties of the synthetic compounds according to the alkyl chain length. The critical micelle concentration is 1.62 × 10-4 to 5.13 × 10-4 mol/L, and the surface tension at the critical micelle concentration is 25.51 to 32.15 mN/m. HLB value of 11 ~ 16 is expected to be applied as an O/W emulsifier. The foaming height was improved with increasing alkyl chain length and emulsion stability was the best in monomer.
저자 신혜린, 정노희
소속 충북대
키워드 gemini surfactant; reactive surfactant; critical micelle concentration; surface tension; foaming height; emulsion stability
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