화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2007년 가을 (10/11 ~ 10/12, 일산킨텍스)
권호 32권 2호
발표분야 기능성 고분자
제목 UV to NIR Chemically and Electrically Tunable Block Copolymer Photonic Gels
초록 Block copolymers are periodic materials that offer advantages as chemically and electrically tunable PBG materials. We employ a polystyrene-b-quartinized poly(2-vinyl pyridine) (PS-b-QP2VP) block copolymer. This mesogel multilayer structure provides for swelling of the QP2VP gel layers while the glassy PS layers force gels to expand uniaxially normal to the layers. This gives extremely large tunability from UV-VIS to NIR region with up to 5th order PBG peaks observed during osmotic induced swelling. Applied electric fields cause electrophoretic transport of the counterions and strong stretching of the end-anchored QP2VP blocks due to electrostatic repulsion.
저자 강영종
소속 한양대
키워드 Photonic Crystal; Block Copolymer; Tunability; Electric Field; Chemical Stimuli
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