| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 가을 (11/04 ~ 11/06, 제주국제컨벤션센터(ICCJEJU)) |
| 권호 |
19권 2호 |
| 발표분야 |
석유화학윤활유_포스터 |
| 제목 |
Fully Renewable Pressure-Sensitive Adhesive System Derived from ε‑Decalactone, L‑Lactide, Epoxidized Soybean Oil, and Rosin Ester |
| 초록 |
Pressure-sensitive adhesives (PSAs) are prepared with plant-based thermoplastic polyester elastomers (TPPEs), rosin ester tackifier, and epoxidized soybean oil plasticizer. Controlled bulk ring-opening transesterification polymerization of ε-decalactone and L-lactide using diethylene glycol as an initiator gives ABA type block polyesters via a one-pot, two-step process with only tin(II) ethylhexanoate. Three semicrystalline poly(L-lactide)−poly(ε-decalactone)−poly(L-lactide) (PLLA−PDL−PLLA) triblock copolymers are prepared containing 100 kg mol−1 PDL midblocks and 8−30 wt % PLLA end blocks with narrow dispersities. The triblocks are combined with the tackifier of 50 wt % and the plasticizer of 15−30 wt %. The thermal, viscoelastic, mechanical and morphological properties of the elastomers and the adhesive formulations are determined. These novel materials could hold promise for sustainability and high adhesive performance. |
| 저자 |
신지훈1, 김영운1, 이경찬2, 이상준3
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| 소속 |
1한국화학(연), 2인하대, 3과학기술연합대 |
| 키워드 |
Pressure-sensitive adhesives; Thermoplastic elastomers
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| E-Mail |
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