화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2016년 봄 (05/02 ~ 05/04, 여수 엑스포 컨벤션)
권호 20권 1호
발표분야 에너지저장변환_포스터
제목 Nanoneedle composites of Carbon-coated Si/MnO2 with optimum carbon layer activation for supercapacitor applications
초록 Carbon-coated Si/MnO2 ternary hybrid composites were fabricated. Initially, a carbon layer was formed directly on the Si surface by thermal vapor deposition. The resulting carbon layer was activated using phosphoric acid to control its surface area and porosity. The degree of activation of the carbon layer was optimized by measuring the specific capacitance of electrodes activated using different phosphoric acid concentrations. The carbon-coated Si electrode made by activation with 3 M phosphoric acid (Si@C(3)) exhibited the highest specific capacitance (117.2 F g1 at 1 A g1). Subsequently, MnO2 nanoneedles were formed on the carbon-coated Si surface with different feed ratios.The Si@C(3)/MnO2 composite formed with a MnO2/Si@C(3) feed ratio of 2:1 (Si@C(3)/MnO2(2)) showed the highest specific capacitance (240.1 F g1 at 1 A g1) of the Si@C(3)/MnO2 composite electrodes. The proposed ternary-hybrid composites can be used for the fabrication of high-performance electrodes.
저자 최재호, 김주헌
소속 중앙대
키워드 supercapacitor; Nanoneedle; Carbon-coated
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