| 학회 | 한국고분자학회 |
| 학술대회 | 2004년 가을 (10/08 ~ 10/09, 경북대학교) |
| 권호 | 29권 2호, p.477 |
| 발표분야 | 고분자 합성 |
| 제목 | Novel Dinuclear Ru-Based Catalysts for Ring Opening Metathesis Polymerization (ROMP) of Polar Norbornene Derivatives |
| 초록 | High transparent polymers from ring opening metathesis polymerization (ROMP) of norbornene derivatives were widely used in optical applications because of their high thermal stability and high clarity. Especially, this excellent properties can be able to use in a suitable core material in the area of plastic optical fiber (POF) for automobile. As the transition metal catalyst for ROMP1,2 has a lower tolerance exposed at moisture and oxygen, many researchers have devoted to develop more stable and more active catalyst for metathesis during the past decade.3 Novel dinuclear Ru-based complexes (DK, 2) have been prepared by simple treatment of Grubbs' catalyst [RuCl2(=CHPh)(PCy3)2, 1] with ligands having two Schiff base groups. These air- and water-tolerant dinuclear complexes (DK) were shown to exhibit an increased ROMP activity at elevated temperature and at the polar solvent system compared to that of the parent complex (1). Also, DK catalyst has a much higher activity in the polymerization of polar norbornene (3) containing ester group than other ROMP catalysts. Reference 1. Michael R. Buchmeiser, Chem. Rev., 100, 1565 (2000) 2. P-Ling Wu et al, Macromol. Chem., 203, 2177 (2002) 3. Robert H. Grubbs et al, Organometallics., 21, 5678 (2002) |
| 저자 | 신성영, 윤성철, 이창진 |
| 소속 | 한국화학(연) |
| 키워드 | Grubb's; Ru; ROMP; Shiff-base; Norbornene |
