| 학회 |
한국고분자학회 |
| 학술대회 |
2008년 가을 (10/09 ~ 10/10, 일산킨텍스) |
| 권호 |
33권 2호 |
| 발표분야 |
고분자 합성 |
| 제목 |
Reversible, 3D-Supramolecular Self-Assembly |
| 초록 |
We synthesized novel azo-conjugated 9,9’-di-tetraethyleneglycol fluorene derivatives containing nitro and amide functional groups at the end of the side chain of oligofluorene for the purpose of making 3D-supramolecular self-assembled aggregates having reversible photo, redox and temperature-responsive properties. The newly synthesized molecules were characterized and confirmed with 1H and 13C-NMR, FT-IR. In addition photophysical properties were measured with UV and PL spectrometer. The LUMO and HOMO energy levels were observed from electrochemical method and also cis-trans isomerization and a half-life of the cis-isomer were analyzed using laser spectroscopy. The formation of duplex and dissociation was efficiently regulated on photo-irradiation without being disturbed by the thermal isomerization. Finally we can be make reversible 3dimentional self assembled structure. |
| 저자 |
아야나 시바, 권영수, 이현준, 박태호
|
| 소속 |
포항공과대 |
| 키워드 |
Supramolecule; Self-Assembly
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| E-Mail |
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