학회 | 한국공업화학회 |
학술대회 | 2022년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터(ICC JEJU)) |
권호 | 26권 1호 |
발표분야 | 포스터-콜로이드·계면화학 |
제목 | Synthesis of biodegradable cationic cellulose nanofibrils as an alternative of conventional cationic surfactants |
초록 | Petrochemical cationic surfactants have shown poor biodegradability, giving rise to accumulation in the aquatic environment. This study was designed to address a novel cationic surfactant, derived from bacterial cellulose nanofibrils, with better biocompatibility. For this, bacterial cellulose (BC) was charged cationically with glycidyltrimethylammonium chloride (GTAC). To enhance amphiphilicity of amine-functionalized BC (ABC), we added 3-aminopropyltriethoxysilane (APTES) using silane-coupling reaction, following the alkylation with stearic acid. The rheological analysis confirmed that C18-ABC generated a fibrillary membrane at the O/W interface and stabilized microemulsion droplets. We also observed CLSM images to highlight the sufficient adhesion of C18-ABC to hair strands. Therefore, we substantiate that natural-based C18-ABC is estimated to have the potential to be an alternative to conventional cationic surfactants with desired interface tunability. |
저자 | 신재원, 서복기, 김진웅 |
소속 | 성균관대 |
키워드 | cellulose nanofibrils; pickering emulsion; cationic cellulose; hair conditioning agents |