화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 봄 (04/07 ~ 04/08, 대전컨벤션센터)
권호 36권 1호
발표분야 기능성 고분자
제목 Colorimetric Detection of Fatty Amines Based on Conjugated Polydiacetylenes
초록 Owing to their intriguing structural and optical properties, conjugated polydiacetylenes (PDAs) have received great attention from researchers. Dropping an organic solution containing diacetylene (DA) monomers into water, followed by sonication yields self-assembled DA supramolecules, which can be readily polymerized by 254 nm UV light. The polymerized DA suspension displays, in general, an intense blue color and undergoes a colorimetric transition to red color upon environmental perturbations. In this study, we developed a colorimetric fatty amine sensor based on conjugated polydiacetylene (PDA) supramolecules in aqueous solution. PDA supramolecules showed blue-to-red or blue-to-orange color transition upon exposure to fatty amines having different alkyl chain lengths. The hydrophobic interaction between aliphatic chains in the polymer and those of fatty amines is believed to cause the colorimetric response.
저자 윤보라, 김광환, 김종만
소속 한양대
키워드 polydiacetylene; fatty amine; sensor
E-Mail