화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2008년 가을 (10/09 ~ 10/10, 일산킨텍스)
권호 33권 2호
발표분야 고분자 구조 및 물성
제목 Thermo-mechanicalbehaviors of epoxidized vegetable oils-modified epoxy resins
초록 Epoxy materials were prepared from diglycidylether of bisphenol-A (DGEBA) and epoxidized vegetable oils (EVO), epoxidized soybean oil and epoxidized castor oil, with a thermally latent initiator. The effects of EVO content on the thermo-mechanical properties of EVO-modified DGEBA epoxy resins were investigated using several techniques. Differential scanning calorimetry indicated that the cure reaction of the DGEBA/EVO systems proceeded via two different reaction mechanisms. Single and composition-dependent glass transition temperature (Tg) were observed for the systems after curing. The experimental values of Tg could be explained by the Gordon-Taylor equation. The thermal stability of the systems decreased as the EVO content increased. The coefficient of thermal expansion of the systems was found to increase linearly with increasing EVO content.
저자 김범용1, 박수진2
소속 1길림화공학원 재료공학과, 2인하대
키워드 biopolymers; epoxy resins; glass transition temperature; coefficient of thermal expansion
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