화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터)
권호 46권 2호
발표분야 고분자합성
제목 Double-Crosslinked Biopolymer-Based Hydrogel for Intelligent Food Packaging
초록 A facile approach is proposed for the fabrication of nitrogen sensitive hydrogels composed of chemically and physically dual-crosslinked TEMPO-oxidized cellulose nanofibers (TEMPO-CNFs). The hydroxyl groups of TEMPO-CNF suspensions were initially crosslinked chemically with epichlorohydrin (ECH), and subsequently crosslinked physically via the strong electrostatic interaction between carboxylate and Ca2+ ions. Then, anthocyanin is successfully conjugated onto the TEMPO-CNF in hydrogel. The colorimetric hydrogels presented visible color changes over time due to a variety of basic volatile amines known as total volatile basic nitrogen (TVB-N). Furthermore, it was found that the optimized TEMPO-CNF films exhibit a good transmittance and good mechanical strength. The resulting interpenetrated polymer network hydrogel could be promising candidate not only to guarantee food freshness but also preventing food spoilage and food-borne diseases.
저자 Hamidreza Pirayesh1, 박병대1, Hossein Khanjanzadeh2
소속 1경북대, 2Kyungpook National Univ.
키워드 Biopolymer; Hydrogel; Nanocellulose; Interpenetrated polymer network; Double crosslinked.
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