| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 봄 (04/23 ~ 04/25, 제주ICC) |
| 권호 |
14권 1호, p.46 |
| 발표분야 |
고분자 |
| 제목 |
Size Control and Registration of Nano-structured Thin Films by Cross-linkable Unit |
| 초록 |
Polymer thin films from cross-linkable PS-b-PMMA copolymers containing reactive BCB functionality were prepared by thermal annealing and subsequent cross-linking at higher temperatures, leading to robust thermoset, nano-structured thin films. By controlling the extent of cross-linking, either by varying the concentration of the BCB or by limiting the extent of cross-linking, a simple route to control the feature size of the microdomains was shown. Multi-layered cross-linked thin films of the BCP were also fabricated where the microphase separation of adjacent layers were in registry, leading to a propagation of the orientation and ordering of the thin film over large distances. This opens a simple route to generate films with 3-dimensional structure with controlled placement of elements. |
| 저자 |
김은혜1, 류두열1, 신창학1, 안형주1, 방준하2, Craig J. Hawker3, Thomas P. Russel4
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| 소속 |
1연세대, 2고려대, 3Material research Laboratory, 4Univ. of California |
| 키워드 |
block copolymer; thin film; cross-linking; pore size control
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| E-Mail |
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| 원문파일 |
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