화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터)
권호 43권 1호
발표분야 대학원생 구두발표 (영어발표, 발표15분)
제목 Molecular Orientation Controlled Planar Heterojunction Organic Photovoltaics
초록 Here, we investigate the influence of interfacial donor-acceptor molecular orientation on photocurrent generation. Planar heterojunction solar cells with orientation-controlled conjugated polymer layers are fabricated and analyzed as a model system. The orientation of polymer chains is modified by controlling solvent evaporation during spin-coating process. The photocurrent generation is more efficient in the device with face-on donor-acceptor interface than the device with edge-on donor-acceptor interface. Photophysical analyses reveal that the molecular orientation affects charge separation at the interface, resulting in enhanced free charge generation in the case of face-on interface. These results emphasize the importance of molecular orientation control for high performance of OSCs.
저자 이한솔, 이동기, 신동훈, 조길원
소속 포항공과대
키워드 organic solar cells; molecular orientation
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