| 초록 |
Microporous organic polymers (MOPs) have attracted great attention due to their ease of synthesis and high surface areas. Structural diversity of MOPs allows for wide applications such as gas adsorption and separation, catalysis, and sensing. Imine bonds, which can be easily formed by condensation of amino and aldehyde groups in the absence of metal catalysts, have nitrogen atoms, which efficiently interact with CO2 molecules. Therefore, MOPs obtained by imine condensation have potential for CO2 adsorption and separation. In this study, imine-linked MOPs were prepared from a cyclotriphosphazene monomer bearing aldehyde groups and aromatic diamines and their pore structures and CO2 uptakes were investigated. |
