화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2013년 가을 (10/30 ~ 11/01, 대전컨벤션센터)
권호 17권 2호
발표분야 포스터-촉매
제목 N-Heterocyclic Carbene/Pd Complex on Graphene Oxide for Suzuki Reaction
초록  We synthesized 3-(3-aminopropyl)-1-methylimidazolium bromide, [APMIm][Br], to functionalize graphene oxide (GO), which was used as a heterogeneous N-heterocyclic carbine (NHC) precursor (denoted GO-NHC). Then, Pd(OAc)2 was immobilized onto GO-NHC to form a Pd/NHC complex (denoted GO-NHC-Pd). The synthesized GO-NHC-Pd was fully characterized by FT-IR, ICP, and XPS. GO-NHC-Pd exhibited its excellent catalytic activity in Suzuki C-C coupling reaction. In addition, GO-NHC-Pd was reused in Suzuki reaction several times without a loss of its catalytic activity.
저자 박정현, Faizan Raza, 전수지, 김혜인, 김종호
소속 한양대
키워드 Pd catalyst; N-heterocyclic Carbene; Suzuki reaction; Graphene Oxide
E-Mail kjh75@hanyang.ac.kr