학회 |
한국공업화학회 |
학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
권호 |
19권 1호 |
발표분야 |
우수논문(구두) |
제목 |
Highly Efficient Blue Emitting Materials Based on Dual Core Chromophores |
초록 |
Highly efficient blue emitting materials consisting of dual core derivatives with phenyl and/or naphthyl side groups and asymmetric or symmetric structures were designed and synthesized. The asymmetric structures 1-naphthalen-1-yl-6-(10-phenyl-anthracen-9-yl)-pyrene (Ph-AP-Na) and 1-(10-naphthalen-1-ylanthracen-9-yl)-6-phenyl-pyrene (Na-AP-Ph), and the symmetric structures 1-phenyl-6-(10-phenylanthracen-9-yl)-pyrene (Ph-AP-Ph) and 1-naphthalen-1-yl-6-(10-naphthalen-1-yl-anthracen-9-yl)-pyrene (Na-AP-Na) were synthesized. Of the synthesized compounds, Na-AP-Na was found to exhibit the highest EL device efficiency of 5.46 cd/A. Ph-AP-Na, Na-AP-Ph, Ph-AP-Ph, and Na-AP-Na exhibit EL maximum values of real blue color in the range 455 nm to 463 nm. The y values of their color coordinates are within the range 0.12 to 0.14, so these compounds exhibit good blue color coordinates for displays. The lifetime of the Na-AP-Na device was more than three times longer than that of the AP dual core (1-anthracen-9-yl-pyrene) device. |
저자 |
이하윤1, 김범진2, 김승호1, 김중한1, 이재현1, 신환규1, 이지훈3, 박종욱1
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소속 |
1가톨릭대, 2한국화학(연), 3한국교통대 |
키워드 |
OLED; Fluorescence; Blue emitter; Dual core
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E-Mail |
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