화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2004년 가을 (10/29 ~ 10/30, 호서대학교(아산캠퍼스))
권호 10권 2호, p.1328
발표분야 분리기술
제목 Dehydration characteristics by pervaporation using a polymeric/ceramic composite membrane for quaternary acetic acid-ethanol-ethyl acetate-water mixtures
초록 A polyetherimide/alumina composite membrane has been prepared by dipping method. Dehydration characteristics by pervaporation using the composite membrane for quaternary equilibrium mixtures of acetic acid-ethanol-ethyl acetate-water have been measured in various temperature and space time at a fixed permeate-side pressure of 2.67x10-3 bar (2 mmHg). Fluxes for the all four components increase as temperature increase tentatively due to the increase of free volume within polymer chains. Apparent activation energies have been obtained for the four components. The flux change for acetic acid is the most sensitive on the temperature change. The composite membrane shows a good dehydration capability.
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소속 LG석유화학(주)
키워드 pervaporation; polymeric-ceramic composite membrane; membrane separation
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