화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 고분자가공/복합재료
제목 Flame retardant rigid polyurethane foams reinforced by iron phosphonate dopamine coated cellulose
초록 Expandable graphite (EG) is a flame retardant material that is useful for polyurethane foam (PUF) synthesis, but it shows the disadvantage of reducing mechanical strength, which limits application field. In this study, to overcome the limitations of EG / PUF composites, cellulose-based flame retardants as a reinforcement were prepared using novel method. The grinded microcrystalline cellulose was coated with mussel-derived adhesive protein, dopamine, and formed an iron phosphonate coordination network on the surface. Grinded microcrystalline cellulose based flame retardant (GCF) was incoporated to the EG / PUF composites and the total content of EG and GCF was adjusted to 15%. The NEAT PUF had a low LOI value of 19.3%, while the PUF mixed with 3 wt% of GCF and 12 wt% of EG (GCF3) had a high LOI value of 25.1%. Especially, the compressive strength of GCF3 was remarkably enhanced (21 wt %) than the PUF containing 15 wt % of EG (EG15).
저자 윤경원, 김성훈
소속 한양대
키워드 flame retardant; polyurethane foam; cellulose; expandable graphtie
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