화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2011년 봄 (05/11 ~ 05/13, 제주국제컨벤션센터)
권호 15권 1호
발표분야 정밀화학
제목 Simple Rapid Method for the Synthesis of γ,γ-Diketophosphonates
초록 We recently reported the synthesis of γ-hydroxy-γ-oxaphosphonates which was obtained by reacting the intermediate oxaphospholene with several aldehyde under neutral and mild conditions.We were able to obtain the phosphonate-containing aldol compounds in fairly good yield in a two-step one-pot reaction.In our attempt to extend our methodology, we now report our synthesis ofγ,γ-diketophosphonates.We have discovered by reacting the oxaphospholene intermediate with various acyl chloride under low temperature gives the desired product in quatitative yield.
저자 김태우1, Tasneem Islam2, 정강연3
소속 1Department of Biochemical Engineering, 2Gangneung-Wonju National Univ., 3Department of Biological
키워드 γ; γ-Diketophosphonates
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