초록 |
Substituted phthalocyanine (Pc) derivatives exhibit good chemical stability, peculiar structural features, and unique coordination properties. In addition, they are well-known for outstanding spectroscopic characteristics and fascinating electrochemical behaviors when combined with selected nano-materials. Herein we present the spectral and electrochemical behaviors of substituted Pcs and their hybrid composite materials. We have carefully designed and manipulated the synthetic routes to prepare symmetrical and unsymmetrical Pc derivatives. In doing so, we were able to provide preferential reaction sites, covalent or noncovalent, for composite formation, and thus enhance the spectral and electrochemical activities. In actual presentation, preparation and properties of Pcs and resulting Pc-based composites will be addressed in detail. |