학회 |
한국고분자학회 |
학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
권호 |
37권 1호 |
발표분야 |
기능성 마이셀 나노구조체 |
제목 |
Photoresponsive Rod-Coil Block Copolymer Micelles |
초록 |
Photoinduced reversible transmittance modulation was achieved with the self-assembled block copolymer micelles. The reversible transmittance changes resulted from photoinduced aggregation and segregation of self-assembled block copolymer micelles composed of well-defined rod-coil type diblock copolymers. The block copolymers were synthesized through CGCP for rod segments containing azobenzene units in the main chain, and subsequent ATRP of styrene with a proper macroinitiator for coil blocks. A large conformational change of the well-defined rod-coil diblock copolymers containing azobenzene and ether groups in the rod block induced a remarkable macroscopic change which can be observed with the naked eye. |
저자 |
김상율, 허재원, 박제영, 문미희
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소속 |
KAIST |
키워드 |
block copolymer; photoresponsive; polymer micelle
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E-Mail |
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