화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자합성-구조제어중합
제목 An Ideal Nanoreactor for Different Architectures of Core-Shell, Alloy, Individual Nanoparticles
초록 We report on synthesis of stable polyelectrolyte complexes (PECs) in aqueous solution, acting as an ideal nanoreactor for synthesis of Au-Ag core-shell as well as Au-Ag alloy nanoparticles. The nanometer-sized PECs (composed of PAH1/PAA0.4) were synthesized by simple mixing of two weak polyelectrolytes, poly(allylamine hydrochloride) (PAH) and poly(acrylic acid) (PAA) in nonstoichiometric ratio (PAH:PAA= 1:0.40) without using sacrificial templates. Subsequently, Au and Ag precursors were loaded on PECs using as nanoreactors for synthesis of core-shell and alloy structures, followed by a successive reduction and a coreduction method, respectively.
저자 샤히눌1, 최원산2, 이하진3, 전일철4
소속 1KBSI, 2한밭대, 3한국기초과학지원(연), 4전북대
키워드 Core-Shell; Alloy
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