학회 |
한국고분자학회 |
학술대회 |
2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터) |
권호 |
36권 2호 |
발표분야 |
고분자합성-구조제어중합 |
제목 |
An Ideal Nanoreactor for Different Architectures of Core-Shell, Alloy, Individual Nanoparticles |
초록 |
We report on synthesis of stable polyelectrolyte complexes (PECs) in aqueous solution, acting as an ideal nanoreactor for synthesis of Au-Ag core-shell as well as Au-Ag alloy nanoparticles. The nanometer-sized PECs (composed of PAH1/PAA0.4) were synthesized by simple mixing of two weak polyelectrolytes, poly(allylamine hydrochloride) (PAH) and poly(acrylic acid) (PAA) in nonstoichiometric ratio (PAH:PAA= 1:0.40) without using sacrificial templates. Subsequently, Au and Ag precursors were loaded on PECs using as nanoreactors for synthesis of core-shell and alloy structures, followed by a successive reduction and a coreduction method, respectively. |
저자 |
샤히눌1, 최원산2, 이하진3, 전일철4
|
소속 |
1KBSI, 2한밭대, 3한국기초과학지원(연), 4전북대 |
키워드 |
Core-Shell; Alloy
|
E-Mail |
|