학회 | 한국화학공학회 |
학술대회 | 2017년 가을 (10/25 ~ 10/27, 대전컨벤션센터) |
권호 | 23권 2호, p.2102 |
발표분야 | 재료 |
제목 | Synthesizing an electron rich modified NHC palladium complex and its catalytic application on Suzuki coupling reaction |
초록 | Suzuki coupling reaction is one of the most important reactions widely used to synthesize polyolefines, styrenes, and substituted biphenyls. Till now, there are tremendous palladium catalysts are applied and developed. As well known, in an aspect of economic, the needs for heterogeneous are inevitable. In order to maximize the catalytic effect of palladium catalyst, many ligands have also developed. Most of the ligands contain nitrogen (primary or secondary amine) or ketone to grasp palladium homogenous catalyst. Here, we designed an electron rich modified NHC palladium complex grafted onto the surface of the graphene oxide. Modified NHC palladium shows better catalytic activity than NHC palladium. The catalyst was characterized by TEM, IR, XPS, and the catalytic yield was measured by using GC. |
저자 | 천영걸, 소재일, 성홍규, 류지형, 심상은 |
소속 | 인하대 |
키워드 | 화공소재 전반 |
원문파일 | 초록 보기 |