화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2011년 가을 (10/06 ~ 10/07, 김대중 컨벤션센터)
권호 36권 2호
발표분야 고분자합성-구조제어중합
제목 Size and Dispersion Control of Polystyrene Spheres using Microemulsion Polymerization
초록 Nanostructured polymer materials have been interested from many researchers for their various applications such as core-shell materials, biological materials, and nanocoating etc,. Polystyrene spheres can be used templates for the mesoporous hollow spheres for further applications such as drug delivery and metal absorption etc. In this work, we investigated the control of polystyrene particle diameter using various amounts of sodium dodecyl sulfate as a surfactant with pentanol as a co-surfactant. On increasing the amount of surfactant, the polystyrene sphere size was decreased (from 240 nm to 35 nm) due to micelle effect to the particle size. From light scattering analysis, the PS spheres have narrow particle size distribution. To prevent aggregation of PS particles, we used dropwise addition of styrene monomer with pentanol to the solution to reduce monomer droplets. Transmission Electron Microscopy (TEM) analysis shows extremely high dispersion of PS spheres with no aggregations.
저자 추상욱, 하창식, 박성수
소속 부산대
키워드 Polystyrene spheres; Microemulsion
E-Mail