화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO))
권호 22권 1호
발표분야 우수외국인연구자세션
제목 Understanding realistic energy densities in supercapacitors with hierarchically porous nitrogen doped graphene
초록 We report synthesis of nitrogen doped three dimensional graphene (N-RGO) architectures. The detailed doping configurations analysed by XPS indicate the nitrogen content of around 6.2 at.%. The reduced graphene oxide has specific surface area of 190 m2 g-1 and specific capacitance up to 217 F g-1 at a scan rate of 5 mV s-1.The low charge transfer resistance confirmed by electrochemical impedance spectroscopy is associated with good rate capability. The N-RGO sample exhibits an excellent cyclic stability with no decay in capacitance even after 5000 cycles at scan rate of 100 mV s-1. A further study for high energy density supercapacitor (SC) is conducted by introducing micro porosity and 1-ethylimidazolium tetrafluoroborate (EMIMBF4) ionic liquid (IL) electrolyte in to the system, which is to be discussed.
저자 Manikantan Kota, 박호석
소속 SKKU
키워드 Supercapacitor; Nitrogen doping; Energy density
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