| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 봄 (04/04 ~ 04/06, 대전컨벤션센터) |
| 권호 |
43권 1호 |
| 발표분야 |
고분자합성 |
| 제목 |
Mechanochemical Post-Polymerization Modification: Solvent Free Solid-State Synthesis of Functional Polymers |
| 초록 |
The post-polymerization was successfully accomplished using the mechnochemical method. Mechanical chemical synthesis is a chemical transformation induced by mechanical forces. The fast and efficient synthesis of a library of macromolecules with functional diversity and structural uniformity was realized without a solvent by means of high speed ball-milling technique. A series of polymers from 4-vinylbenzaldehyde(4-VBA) reacted with a series of amines and derivatives to form solid-state Schiff base. The efficient mixing and energy delivery by the collisions between balls not only promoted prompt imine formation but also eliminated the need of chemical solvent, which is highly desirable for green chemical synthesis. |
| 저자 |
온누리, 김정곤
|
| 소속 |
전북대 |
| 키워드 |
post-polymerization; mechanochemistry
|
| E-Mail |
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