| 초록 |
The natural photosynthetic process has fascinated chemists for long due to its high specificity in solar energy conversion to sugar. However, given the structural and functional complexity, it is a challenge to mimic this natural process. Nonetheless, efforts to develop efficient photosynthesis mimetic systems have been going on since 1970s. In recent years, these efforts have intensified due to increasing emphasis on the development of carbon-free or carbon-neutral systems/technologies for production of solar fuel/chemicals. In this regard, we developed the photocatalyst/enzyme integrated solar chemical factory platform system that exemplified solar energy in synthesis of solar fuel & solar chemicals. Generating NAD(P)H in non-enzymatic light-driven process and coupling it to the enzymatic dark reaction catalysis for the tailor-maid solar chemical synthesis via photobiocatalysis. The present work demonstrates successfully a new and potentially promising solar solar chemical factory platform system for the ultimate goal of utilization of solar energy in fuel & fine chemical synthesis. |
