화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2013년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 38권 2호
발표분야 기능성 고분자 (포스터발표만 진행)
제목 A facile synthesis of crumpled adsorbent via free radical polymerization for removal heavy metal ions
초록 In recent years, a variety of strategies to effluent stream treatment through organic ligand have been researched. Adsorption of heavy metal ions has been researched based on the covalent grafting of functional group complexes. We synthesized grafting polymer functionalized with amine group which has strong affinity to metal ions. The crumpled polymer is an efficient material for collecting metal ions from aqueous stream like wastewater. To synthesis crumpled poly (allylamine-co-methacrylic acid), all components are prepared in aqueous system and polymerized via free radical polymerization. Structure is identified by 1H-NMR and FT-IR. The thermal characteristic is confirmed by TGA and DSC. On the continuous stirring process, selectivity and adsorption capacity of crumpled polymer are studied by ICP-OES and UV-vis spectroscopy. At the point of easy process and distinctive morphology, enhanced adsorption property makes them suitable alternatives for organic adsorbent.
저자 정세영1, 김용석1, 정인우2, 김중현1
소속 1연세대, 2경북대
키워드 crumpled polymer; chelate; radical polymerization; adsorption; selectivity; synthesis
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