화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 가을 (10/11 ~ 10/12, 창원컨벤션센터)
권호 37권 2호
발표분야 고분자합성
제목 A Study on the Preparation and Thermal Property of Microencapsulated Poly(ethylene glycol) Phase with Inverse Emulsion Polymerization
초록 Poly(ethylene glycol) (PEG) has been a promising candidate of phase change material(PCM) for thermal energy storage and temperature control in the field of construction and transportation, because it shows relatively large heat of fusion, congruent melting behaviour, and wide melting point ranging from ca. 0℃ to 70℃ depending on its molecular weight. In addition, it is intrinsically biocompatible due to its chemical structure. In this study, PCM capsules with PEG core and polymer shell were prepared. For the microencapsulation of PEG, is selected so-called inverse emulsion polymerization method. The parameters influencing the thermal properties of PCM PEG core were investigated as functions of monomers’ polarity, amount of crosslinkers and surfactant, and the ratio of PCM to monomer. The detailed thermal properties are analysed with aids of DSC, SEM, and other apparatus.
저자 신대철, 김정수
소속 녹색에너지기술전문대
키워드 PCM; PEG; inverse emulsion; thermal energy storage
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